Message "error 205" usually appears on Android devices when trying to link to another Sync identity.
This error means that the current Sync identity on the Android got corrupted, and thus it cannot get replaced with a new one.
To fix that, in Sync on this Android device go to menu: "☰ > Settings > Identity > Unlink from identity":
After that, create a new identity and give it a name, any. When the new non-corrupted identity is created, scan the QR code again to link this Android device to another Sync identity.